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Journal of Dental Research, Vol 69, 849-851, Copyright © 1990 by International & American Associations for Dental Research Online Journals


ARTICLES

Monomer composition and bond strength of light-cured 4-META opaque resin

K. Yoshida, H. Matsumura and M. Atsuta
Department of Fixed Prosthodontics, Nagasaki University School of Dentistry, Japan.

A light-cured opaque resin was prepared with 4-(2-methacryloxyethoxycarbonyl) phthalic anhydride (4-META), bifunctional methacrylates, and titanium dioxide (TiO2). The relation between monomer composition and bond strength was examined with seven methacrylate monomers. Methyl methacrylate (MMA) was useful as a solvent of 4-META. However, it was not sufficiently cured by photo-initiator. The bond strength of a triethyleneglycol dimethacrylate (TEGDMA)-based composition was superior to other monomer-based compositions after repeated thermocycles. 1,6-bis(methacryloxy-2-ethoxycarbonyl-amino)-2,4,4-trimethylhex ane (UDMA) effectively provided viscosity to the composition. The prepared opaque resin consisted of 4-META/MMA-TEGDMA primer, TEGDMA-UDMA-based monomer, and titanium dioxide. This opaque resin bonded strongly to alumina-blasted cobalt-chromium alloy. The light-cured 4-META opaque resin may be useful for bonding prosthodontic composite to metal frameworks.





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