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Journal of Dental Research, Vol 65, 437-440, Copyright © 1986 by International & American Associations for Dental Research Online Journals

ARTICLES

Micro-Raman line broadening in synthetic carbonated hydroxyapatite

F. F. de Mul, M. H. Hottenhuis, P. Bouter, J. Greve, J. Arends and J. J. ten Bosch

Using a Raman microspectrometer, we have recorded Raman spectra of synthetically produced hydroxyapatite samples with varying carbonate contents. The apatites were produced from aqueous solutions at about 40 degrees C. From line-broadening values of the symmetric phosphate stretch, it was concluded that the carbonate substitution in these lattices has a maximum of 4.5 wt %. Both phosphate and hydroxyl ions seem to be involved in the carbonate substitution process.


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M. C. M. De Toledo, S. L.R. Lenharo, V. C. Ferrari, F. Fontan, P. De Parseval, and G. Leroy
THE COMPOSITIONAL EVOLUTION OF APATITE IN THE WEATHERING PROFILE OF THE CATALAO I ALKALINE-CARBONATITIC COMPLEX, GOIAS, BRAZIL
Can Mineral, August 1, 2004; 42(4): 1139 - 1158.
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