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J Dent Res 53(6): 1414-1419, 1974
© 1974 International and American Associations for Dental Research
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Reactions in Glass Ionomer Cements: II. An Infrared Spectroscopic Study

STEPHEN CRISP 1, MARTIN A. PRINGUER 1, DION WARDLEWORTH 1, and ALAN D. WILSON 1

1 Laboratory of the Government Chemist, Department of Trade and Industry, Cornwall House, Stamford Street, London SE1 9NQ, England

The transmission and attentuated total reflectance spectra of a dental cement formed from an aluminosilicate glass and aqueous polyacrylic acid (ASPA) are reported. Interpretation of spectra show that a siliceous hydrogel is formed together with the polyacrylate salts of calcium and aluminum. In the fully hardened cement a minor proportion of -COOH remains unconverted to -COO-groups for steric reasons.

Submitted on August 17, 1973






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