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J Dent Res 47(4): 644-652, 1968
© 1968 International and American Associations for Dental Research
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Dental Silicate Cements: VI. Infrared Studies

ALAN D. WILSON 1 and ROBERT J. MESLEY 1

1 Dental Materials Section, Laboratory of the Government Chemist, Cornwall House, Stamford Street, London, S.E.I, England

Infrared studies have shown that silica gel and H2PO4-1 ions are formed in fresh cement paste. Subsequently, during setting and hardening, H2PO4-1 ions further react to form covalent phosphates and are removed from the system. In an uncertified cement, H2PO4-1 ions were found in substantial amounts even in the set cement, which accounted for poor strength and durability.

Submitted on February 5, 1968






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